Last updated: 8 October 2026
The Periodic Table allows us to predict chemical behaviour. We do not need to memorise every element separately. Once we understand why elements in the same group behave similarly, the position of an element becomes a useful clue to its reactions and properties.
Group 1, Group 17 and Group 18 illustrate this particularly well. Group 1 metals readily lose electrons, Group 17 halogens tend to gain electrons, while Group 18 noble gases already have filled outer electron shells and are therefore very unreactive.
The important skill is not simply remembering that one group becomes more reactive while another becomes less reactive. We want to understand what the elements actually do, recognise their characteristic properties and use the group trends to make predictions.
Try these five questions before reading the chapter. They test the electron ideas that help explain the behaviour of Groups 1, 17 and 18.
- 5 diagnostic questions
- Important misconceptions tested
- Instant explanation for every answer option
Why group position predicts chemical behaviour
A group is a vertical column in the Periodic Table. For the main-group elements studied here, the group tells us something very important about the electrons in the outermost occupied shell.
Group 1 atoms have one outer-shell electron. Group 17 atoms have seven. Group 18 atoms have filled outer electron shells.
This matters because chemical reactions usually involve changes in the outer electrons. An atom may lose electrons, gain electrons or share electrons with another atom. The arrangement of the outer electrons therefore helps determine how an element reacts.
The group-property principle
Elements in the same group have similar chemical properties because their atoms have the same number of outer-shell electrons.
| Group | Outer-shell arrangement | Typical electron behaviour | Typical result |
|---|---|---|---|
| Group 1 | 1 outer-shell electron | Loses 1 electron | Forms a 1+ ion |
| Group 17 | 7 outer-shell electrons | Gains 1 electron | Forms a 1− ion |
| Group 18 | Filled outer shell | Little tendency to lose, gain or share electrons | Very unreactive |
Elements in the same group are similar, but they are not identical. Moving down a group adds another occupied electron shell. The atoms therefore become larger, and the outer electrons experience more shielding from inner-shell electrons. These changes produce the trends that we observe.
Group 1: the alkali metals
Group 1 contains metals such as lithium, sodium and potassium. They are called the alkali metals because they react with water to produce soluble metal hydroxides, giving alkaline solutions.
Electronic structure and ions
Every Group 1 atom has one electron in its outer shell. During a chemical reaction, it can obtain a stable electron arrangement by losing this electron.
Sodium therefore forms Na⁺ ions. In the same way, lithium forms Li⁺ and potassium forms K⁺.
Atom versus ion
Group 1 atom: has one outer-shell electron.
Group 1 ion: has lost that electron and carries a 1+ charge.
Physical properties of Group 1 metals
Lithium, sodium and potassium are metals, so they conduct electricity and have a shiny metallic surface when freshly cut. However, they are unusual compared with familiar structural metals such as iron.
The first three Group 1 metals are:
- soft and can be cut with a knife;
- relatively low in density;
- relatively low in melting point compared with many other metals; and
- very reactive, so freshly cut surfaces quickly become dull in air.
Lithium, sodium and potassium are all less dense than water, so pieces of these metals float when placed on water.
Physical trends down Group 1
| Property | Trend down Group 1 |
|---|---|
| Atomic size | Increases |
| Softness | Generally increases |
| Melting point | Decreases |
| Reactivity | Increases |
| Density | Generally increases, although the trend is not perfectly regular |
Be careful with density. The general pattern is an increase down the group, but potassium is less dense than sodium. Density should therefore not be treated as a perfectly smooth trend.
Why does the melting point decrease down Group 1?
Down the group, the metal ions become larger while each still carries a 1+ charge. The attraction between the positive metal ions and the delocalised electrons becomes weaker.
Less energy is therefore needed to overcome the metallic bonding, so the melting point decreases.
Melting-point trend in Group 1
Down the group, the metal ions become larger, metallic bonding becomes weaker, and the melting point decreases.
Reaction of Group 1 metals with water
Group 1 metals react with cold water to form a metal hydroxide and hydrogen gas.
If M represents a Group 1 metal:
For sodium:
Sodium hydroxide dissolves in the water. The resulting solution is alkaline because it contains OH⁻ ions.
Hydrogen can be confirmed using a lighted splint. The gas burns with a squeaky pop.
Comparing lithium, sodium and potassium with water
| Metal | Typical observations | Relative reactivity |
|---|---|---|
| Lithium | Floats, fizzes and moves across the water. It gradually becomes smaller and disappears. | Least reactive of the three |
| Sodium | Floats, fizzes more vigorously and moves rapidly. The heat released can melt the sodium into a small silvery ball. | More reactive than lithium |
| Potassium | Reacts very vigorously and usually ignites, producing a characteristic lilac flame. | Most reactive of the three |

Notice that all three metals undergo the same type of reaction. What changes is the vigour of the reaction. This is exactly what we expect from elements in the same group: similar chemical behaviour, but a systematic change in reactivity.
Why does reactivity increase down Group 1?
A Group 1 metal reacts by losing its single outer-shell electron. Therefore, the easier it is to remove this electron, the more reactive the metal is.
As we move down Group 1:
- the number of occupied electron shells increases;
- the outer electron is farther from the nucleus;
- shielding by inner-shell electrons increases; and
- the attraction between the positive nucleus and the outer electron becomes weaker.
The outer electron is therefore lost more easily. This is why potassium is more reactive than sodium, and sodium is more reactive than lithium.
Reactivity trend in Group 1
More electron shells → greater distance and shielding → weaker attraction for the outer electron → electron lost more easily → greater reactivity.
Group 17: the halogens
Group 17 contains the halogens. Familiar examples include fluorine, chlorine, bromine and iodine.
Unlike Group 1, the halogens are non-metals. Their atoms have seven outer-shell electrons, so their chemical behaviour commonly involves gaining one electron rather than losing one.
Halogen molecules and halide ions
The halogens exist as diatomic molecules. Each molecule contains two atoms joined together.
During many reactions, a halogen atom gains one electron and forms a halide ion with a 1− charge.
It is important to distinguish the element from its ion.
Halogen versus halide
Chlorine: Cl₂, a diatomic element.
Chloride: Cl⁻, a negatively charged ion.
Similarly, bromine is Br₂ while bromide is Br⁻, and iodine is I₂ while iodide is I⁻.
Colours and physical states of the halogens
The physical properties of the halogens change steadily down Group 17. The elements become darker in colour, while their melting points and boiling points increase.
| Halogen | State at room temperature | Appearance of the element |
|---|---|---|
| Chlorine, Cl₂ | Gas | Yellow-green |
| Bromine, Br₂ | Liquid | Red-brown |
| Iodine, I₂ | Solid | Grey-black; forms a purple vapour when heated |
The change in physical state at room temperature can be summarised as:
Moving down the group, the halogen molecules become larger and contain more electrons. The attractive forces between neighbouring molecules become stronger.
More energy is therefore required to separate the molecules. The melting points and boiling points increase down the group.
Physical trend in Group 17
Down Group 17, the molecules become larger and intermolecular attractions become stronger. More energy is needed to separate the molecules, so melting points and boiling points increase.
The covalent bond inside each Cl₂, Br₂ or I₂ molecule is not broken when the substance melts or boils. It is the attraction between separate molecules that is overcome.
Why does reactivity decrease down Group 17?
A halogen reacts by gaining an electron. The more strongly a halogen atom attracts an incoming electron, the more reactive it is.
As we move down Group 17:
- the number of occupied electron shells increases;
- the outer shell becomes farther from the nucleus;
- shielding by inner-shell electrons increases; and
- the attraction between the nucleus and an incoming electron becomes weaker.
The atom therefore gains an electron less readily. Reactivity decreases down Group 17.
Reactivity trend in Group 17
More electron shells → greater distance and shielding → weaker attraction for an incoming electron → electron gained less readily → lower reactivity.
Why are the Group 1 and Group 17 trends opposite?
Down both groups, atomic size and shielding increase. However, the atoms are trying to do different things.
| Group | What the atom does | Effect of weaker attraction down the group | Reactivity trend |
|---|---|---|---|
| Group 1 | Loses an outer electron | The electron becomes easier to lose | Increases |
| Group 17 | Gains an incoming electron | The incoming electron is attracted less strongly | Decreases |
Therefore, simply memorising “more shielding down a group” is not enough. You must ask whether the element reacts by losing an electron or by gaining one.
Halogen displacement reactions
The reactivity order of the halogens can be demonstrated using displacement reactions.
A more reactive halogen can displace the halide ions of a less reactive halogen from solution.
The halogen displacement rule
A halogen can displace halide ions belonging to a halogen below it in Group 17.
For example, chlorine is more reactive than bromine. Chlorine therefore displaces bromide ions from potassium bromide solution.
Potassium ions do not take part in the chemical change. The ionic equation is:
Bromine is formed, so an orange solution is observed.
Chlorine can also displace iodide ions:
Iodine in water gives a brown colour.

Predicting halogen displacement reactions
Instead of memorising every possible reaction, begin with the reactivity order:
Then ask: Is the added halogen more reactive than the halogen represented by the halide ion?
| Halogen added | Chloride ions, Cl⁻ | Bromide ions, Br⁻ | Iodide ions, I⁻ |
|---|---|---|---|
| Cl₂ | No displacement | Br₂ formed | I₂ formed |
| Br₂ | No displacement | No displacement | I₂ formed |
| I₂ | No displacement | No displacement | No displacement |
Use reactivity, not physical state
Correct reasoning: chlorine displaces Br⁻ because chlorine is more reactive than bromine.
Incorrect reasoning: chlorine displaces Br⁻ because chlorine is a gas and bromine is a liquid. Physical state does not determine which halogen is more reactive.
Group 18: the noble gases
Group 18 contains helium, neon, argon and the other noble gases. Their chemical behaviour is very different from Groups 1 and 17 because their atoms already have filled outer electron shells.
Why are noble gases very unreactive?
Helium has two electrons in its first and only shell, so that shell is filled. Neon, argon and the noble gases below them have eight electrons in their outer shells.
Because the outer shell is already filled, a noble-gas atom has little tendency to lose electrons, gain electrons or share electrons with another atom. Noble gases are therefore very unreactive.
A stable outer electron shell
Noble gases are very unreactive because their atoms already have filled outer electron shells.
At O-Level, noble gases are normally treated as very unreactive under ordinary conditions. Some heavier noble gases can form compounds under unusual conditions, but this is not needed for the standard Group 18 chemistry here.
Noble gases are monatomic
Noble gases exist as separate atoms rather than as molecules. They are described as monatomic.
This contrasts with the Group 17 halogens, which exist as diatomic molecules such as Cl₂ and Br₂.
Physical trends down Group 18
Noble gases have very low melting points and boiling points. Moving down the group, however, the atoms become larger and contain more electrons.
Attractions between neighbouring atoms become stronger, so more energy is needed to separate them. Their melting points and boiling points therefore increase down the group.
Their densities also increase down the group as the atoms become progressively more massive.
Uses of noble gases
A good Chemistry answer should connect a use to the property that makes the substance suitable. For noble gases, their very low reactivity is particularly important.
| Noble gas | Use | Why it is suitable |
|---|---|---|
| Helium | Balloons | Helium has a low density and is non-flammable, making it safer than hydrogen. |
| Neon | Advertising signs and discharge lamps | Neon emits characteristic light when an electric current passes through it at low pressure. |
| Argon | Filament lamps | Argon is very unreactive, so it reduces unwanted reaction of the hot metal filament. |
| Argon | Protective atmosphere during welding | Argon provides an unreactive atmosphere around hot metals. |
Always connect a use to a property
Incomplete: Argon is used in filament lamps because it is a noble gas.
Better: Argon is used because it is very unreactive, so it does not readily react with the hot filament.
Comparing Groups 1, 17 and 18
The three groups become much easier to remember when their main features are placed side by side.
| Feature | Group 1 | Group 17 | Group 18 |
|---|---|---|---|
| Type of element | Metal | Non-metal | Non-metal |
| Outer-shell electrons | 1 | 7 | Filled outer shell |
| Usual electron behaviour | Loses 1 electron | Gains 1 electron | Little tendency to lose or gain electrons |
| Typical ion | 1+ | 1− | No common simple ion |
| Structure of the element | Giant metallic structure | Diatomic molecules | Separate atoms |
| Reactivity down the group | Increases | Decreases | Remains very low |
Predicting the properties of unfamiliar elements
One of the most useful features of the Periodic Table is prediction. If you know the position of an unfamiliar element and understand the trend in its group, you can make sensible predictions without having studied that element directly.
A reliable method is:
- Identify the group. This tells you the outer electron arrangement and general chemical behaviour.
- Identify the relevant trend. Decide whether the property increases or decreases down the group.
- Locate the unfamiliar element. Decide whether it lies above or below an element whose properties you know.
- Apply the trend and justify the prediction.
Worked prediction: rubidium
Rubidium lies below potassium in Group 1.
Since Group 1 metals become more reactive down the group, rubidium should be more reactive than potassium. Its outer electron is farther from the nucleus and more strongly shielded, so it is lost more easily.
Rubidium should therefore react very vigorously with water to form rubidium hydroxide and hydrogen.
Worked prediction: an element below iodine
Suppose an unfamiliar element lies below iodine in Group 17. Applying the Group 17 trends, we would predict that it:
- is less reactive than iodine;
- has a higher melting point and boiling point than iodine;
- has a darker appearance; and
- is likely to be a solid at room temperature.
The important skill is the reasoning. We know the direction of the trend and apply it to an element lower in the same group.
Common mistakes in group-property questions
| Common mistake | Why it is wrong | Better idea |
|---|---|---|
| Using the same reactivity trend for Groups 1 and 17. | The two groups react by different electron changes. | Group 1 loses an electron more easily down the group, while Group 17 gains an electron less easily. |
| Saying Group 1 becomes more reactive simply because the atoms are larger. | Atomic size alone does not complete the explanation. | Explain greater distance and shielding, weaker attraction and easier loss of the outer electron. |
| Saying Group 17 becomes more reactive because shielding increases. | Greater shielding weakens attraction for an incoming electron. | State that Group 17 becomes less reactive down the group. |
| Writing Cl⁻ when elemental chlorine is required. | Cl⁻ is a chloride ion rather than chlorine. | Write chlorine as Cl₂ and chloride as Cl⁻. |
| Using physical state to decide whether a halogen displacement occurs. | Displacement depends on relative reactivity rather than whether a halogen is a gas, liquid or solid. | Compare the positions of the halogens in Group 17. |
| Saying boiling iodine breaks the covalent I–I bond. | The iodine molecules remain intact during a physical change. | State that intermolecular attractions between I₂ molecules are overcome. |
| Saying noble gases have empty outer shells. | Their low reactivity comes from a filled outer shell. | State that helium has a filled first shell and the other noble gases have filled outer shells. |
| Giving a noble-gas use without explaining the relevant property. | The chemical reason for the use is missing. | Link the use to a property, such as argon's very low reactivity. |
| Calling the density trend in Group 1 perfectly regular. | Potassium is less dense than sodium. | Describe density as generally increasing down the group, with exceptions. |
Group properties checklist
Understanding groups
- Can I explain why elements in the same group have similar chemical properties?
- Can I link group position to outer-shell electrons?
- Can I distinguish a shared property from a trend down a group?
- Can I use a known trend to predict an unfamiliar element?
Group 1
- Can I explain why Group 1 metals form 1+ ions?
- Can I write the reaction of a Group 1 metal with water?
- Can I compare lithium, sodium and potassium reacting with water?
- Can I explain why reactivity increases down the group?
Group 17
- Can I write halogens as F₂, Cl₂, Br₂ and I₂?
- Can I state the colour and physical-state trends?
- Can I explain why reactivity decreases down the group?
- Can I predict halogen displacement reactions?
Group 18
- Can I explain why noble gases are very unreactive?
- Can I explain what monatomic means?
- Can I describe physical trends down Group 18?
- Can I link helium, neon and argon uses to suitable properties?
These ten questions go beyond simple recall. Use electronic configuration, observations and group trends to reason your way to each answer.
- 10 mastery questions
- Application and misconception testing
- Instant explanation for every answer option
Frequently asked questions
Questions students often ask about group properties
Once the main trends are clear, most remaining difficulties come from explaining why those trends occur or applying them to unfamiliar situations.
Do all elements in the same group have exactly the same properties?
No. They have similar chemical properties because they have the same number of outer-shell electrons. However, properties such as atomic size, melting point, boiling point, density and reactivity change as you move down the group.
Lithium and potassium, for example, both react with water to form a hydroxide and hydrogen, but potassium reacts much more vigorously.
Why are Group 1 metals stored under oil?
Group 1 metals react readily with substances in the air, including oxygen and water vapour. Storing them under oil reduces contact with air and moisture.
Why does sodium form a ball when it reacts with water?
The reaction between sodium and water releases heat. Sodium has a relatively low melting point, so this heat can melt it. The molten sodium forms a small approximately spherical droplet on the water surface.
Why do Group 1 and Group 17 show opposite reactivity trends?
Down both groups, atomic size and electron shielding increase. For Group 1, this makes the outer electron easier to lose, so reactivity increases.
For Group 17, the nucleus attracts an incoming electron less strongly, so the electron is harder to gain and reactivity decreases.
Why are halogens written as Cl₂ and Br₂ instead of Cl and Br?
Elemental halogens exist as diatomic molecules. Each molecule contains two halogen atoms joined by a covalent bond, so chlorine is Cl₂ and bromine is Br₂.
Do not confuse these molecules with the halide ions Cl⁻ and Br⁻.
Why can chlorine displace bromide ions but bromine cannot displace chloride ions?
Chlorine is more reactive than bromine, so Cl₂ can gain electrons from Br⁻ ions and form Cl⁻ ions. Bromine is less reactive than chlorine, so Br₂ cannot remove electrons from Cl⁻ ions.
The direction of the reaction follows the Group 17 reactivity order.
Why may iodine be described as grey-black, brown or purple?
The observed colour depends on the physical form and surroundings. Solid iodine is grey-black, iodine vapour is purple, and iodine dissolved in water appears brown.
Always read the experimental conditions before stating the expected colour.
Are noble gases completely unable to react?
At O-Level, noble gases are treated as very unreactive because their atoms have filled outer electron shells.
Some heavier noble gases can form compounds under unusual conditions, but this does not change the explanation required for ordinary O-Level Chemistry.
Why is helium safer than hydrogen for filling balloons?
Both gases have low densities, but helium is very unreactive and non-flammable. Hydrogen is flammable and can form explosive mixtures with air, so helium is safer.
How should I answer a question asking me to predict the property of an unfamiliar element?
First identify the group. Then state the known trend and locate the unfamiliar element relative to elements whose properties are known. Finally, apply the trend and, where required, explain it using electron shells, shielding and nuclear attraction.
A prediction is strongest when it is justified rather than presented as an unsupported guess.
Group properties show why the Periodic Table is such a powerful tool. Group 1 metals become more reactive because their outer electron becomes easier to lose, while Group 17 halogens become less reactive because an incoming electron is attracted less strongly. Group 18 atoms already have filled outer electron shells and are therefore very unreactive. Once you connect these patterns to electronic configuration, you can move beyond memorising individual facts and begin predicting the chemistry of unfamiliar elements.
